If the skunks sprayed your dogs in the face flush out any spray residue that may have gotten. There are several methods for getting rid of the skunks' smell on the dog. First use 1-quart hydrogen peroxide,1/4 cup baking soda, and 1 teaspoon dish soap. Mix this together. Wash your dog with the mixture immediately after he's been sprayed. Wearing rubber gloves, rub the mixture into your dog's coat, and make sure to avoid his eyes. Wait about 20 minutes before washing the mixture out of your dog's fur. Follow up by bathing your dog with a dog shampoo, and rinse well. Repeat the process 2-3 more times as needed.