Electrons were not originally called "positive" when they were discovered because at the time, scientists believed that all matter was composed of atoms that were made up of positive charges. The existence of negative charges (i.e. electrons) was not yet known.
In the late 18th century, Benjamin Franklin proposed a theory of electricity in which he suggested that electricity was composed of two types of charges: positive and negative. He believed that "vitreous" electricity (i.e. electricity that flowed from a glass rod when it was rubbed with a silk cloth) was positive, and that "resinous" electricity (i.e. electricity that flowed from an amber rod when it was rubbed with a wool cloth) was negative. This theory was based on the observation that when a glass rod was rubbed with a silk cloth, it attracted small objects (such as pieces of paper), while an amber rod rubbed with a wool cloth repelled small objects.
Franklin's theory of positive and negative charges was later refined by other scientists, who discovered that the positive and negative charges were actually carried by separate particles. In the early 19th century, John Daniell discovered the existence of negative charges, which he called "electrons." Later, J.J. Thomson discovered that electrons were a fundamental part of the atom and were much smaller than the positive charges. This led to the development of the modern understanding of atomic structure, in which atoms are composed of a small, dense nucleus of protons (positive charges) and neutrons (neutral charges), surrounded by a cloud of electrons.