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Who is the first Super Villain in Superman?

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The first Super Villain in Superman is Lex Luthor. He is a brilliant scientist and businessman who is bent on world domination. He is Superman's arch-nemesis and is one of the most iconic Super Villains of all time.
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The first super villain that Superman faced in the comics was Lex Luthor. He first appeared in Action Comics in 1940, and has since become one of Superman's most well-known and persistent adversaries. 

Luthor is a brilliant and ruthless scientist who uses his intelligence and resources to challenge Superman both physically and mentally. 

He has been portrayed in various media adaptations over the years, including films, TV shows, and video games.

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The first super villain that Spider-Man encountered was the infamous "Vulture". In the first issue of "The Amazing Spider-Man" comic book series, which was published in 1963, Spider-Man faced off against Vulture (Adrian Toomes), who used his original flying suit to carry out a series of robberies across the city. Spider-Man defeated Vulture after an intense battle in the air, and this marked the beginning of his long list of battles with some of the greatest super villains in the Marvel Universe.
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